2014 Abstracts
Micropropagation studies of Calochortus species
María Velasco, Utah Valley University Agriculture Calochortus is a plant genus that includes approximately 60 species distributed in North America with great ornamental and ethnotobanical value. Sego lily, mariposa lily and other common names have been used to describe the different species of Calochortus. Native Americans and settlers have used the bulbs as food, either raw or ground into flour and cooked. C. nuttallii played an important role in the success of colonization of Utah. Between 1840 and 1851 the scarcity of food due to a plague of crickets led to the pioneers to dig for the bulbous roots of sego lily, ensuring the survival of the pioneer population. This research studies the effects of Gibberellic acid on the germination and elongation of these species in vivo and in vitro. Eight different species of Calochortus are being utilized for this experiment to evaluate the effect of this growth regulator on the germination of these species. Different types of media are being tested to evaluate the optimal in vitro conditions that these species require for germination and growth. In addition embryogenesis and organogenesis is being induced by using Benzyl Amino Purine and 2,4-Dichlorophenoxyacetic acid at different concentrations. Sego Lily is the State flower of Utah; micropropagating this plant will allow us to understand and research new methods and conditions to grow these species successfully, making preservation possible since some Calochortus species have been listed as endangered. In addition, other species such as Calohortus ambiguous (Doubting Mariposa Lily), which is distributed in Utah, Arizona and New Mexico, will also benefit from the system developed in this research because they are closely related to Sego Lily (C. nuttallii). The long term goal of this research is to establish an appropriate micropropagation system for a wide variety of Calochortus species.
Hook-up culture: a qualitative analysis of sexual scripts within gender and religious identidies
Sarah Dursteler, Weber State University Communications The culture of sex outside intimate relationships including dating scripts and sexual scripts has shifted to one of more ambiguity. Multiple changes in sexual scripts have occurred in the last 50 years with the diversification of types of relationships in which sex occurs, including, a greater acceptance of sex outside of relationships (Gagnon & Simon, 1987). This study is in response to the call for more research on how social identities influence perceptions of sexual interaction (Backstrom, Armstrong, and Puentes, 2012). The purpose of this study is to examine hook-up culture outside of traditional intimate relationships. This study explores the extent of the shift from traditional dating scripts to a culture of hooking up as perceived by males and females that identify with the predominant Latter-Day Saint (LDS) religious culture. Using the tenants of social exchange and scripting theories this study examined the attitudes of males and females. Transcripts from four same gender and religion focus groups and 100 open-ended survey responses provided data for analysis. The constant comparative method (Glaser and Strauss, 1967) provided the means by which to analyze data within emergent categories. One open-ended response question was reviewed to assess content theme analysis. The constant comparative method indicated distinct contrast of perceptions of sexual intimacy between males and females. Findings suggest that there are distinct differences between male and female and LDS and non-LDS attitudes about and perceptions of hook-up culture. These results are consistent with previous research indicating that hooking-up can be a functional strategy used to shift focus from traditional intimate relationships to more academic and professional goals.
Cultivation theory and video games: The effect of video games on perception
Taylor Topham, Dixie State University Communications With the new generations comes new forms of entertainment. Rarely is there a home without a television. The Cultivation Theory presented by George Gerbner and his colleagues states that television is so common in our society that it has an affect on our perceptions of the world. The Cultivation Theory specifically looks at violence on television and its effects on the viewer. Those that are heavy viewers of television often have what is known as mean-world syndrome. Because of the violence they watch on television, they are more likely to see the world as a violent place (Littlejohn & Foss, 2011). Along with a television often comes some type of video gaming system. Studies state that over 65% of North American households now have a video gaming system (Chiawen, Aiken & Huang, 2012). The purpose of this research is to determine if video gaming effects the perception of individuals similarly to that of television as described by George Gerbner’s Cultivation Theory.
Change, Conflict and Community in Utah’s West Desert: Industrialization in Tooele as Portrayed by Community Newspapers
Emma Penrod, Brigham Young University Communications A newspaper is the catalog of a community’s past. I spent about three years researching the impact of industrialization on Tooele from a variety of angles, primarily by reading archived newspapers from 1905 to 1970. During this time, I also collected and scanned nearly 200 original photographs. Industrialization came to Tooele in force in 1908, with the construction on the International Smelter and the Tooele Valley Railroad. Prior to the railroad and the smelter, Tooele was a small, predominantly Mormon community with an agrarian economy. Construction of the railroad, the smelter, and several affiliated projects could have employed 72 percent of every man, woman and child living in Tooele City in the early 1900s. An influx of immigrants changed the social landscape dramatically, reshaping Tooele as one of Utah’s most diverse communities. Through the early 1900s, conflict between the original Mormon settlers and the transplants embroiled the community in something of a perpetual identity crisis. Temporarily, a sort of physical segregation solved the problem-Mormons lived west of Main Street, and the immigrants set up shop east of Main Street. But it wouldn’t be long before the Tooele newspapers came to accept the newcomers and the advertising revenue they had to offer. The Great Depression and football, of all things, finally brought the community back together, and throughout the 1940s and 1950s, the immigrant families were invited to fly their native colors at important community events that celebrated Tooele’s heritage.
The Effects of Photographic versus Computer Mediated Video Stimuli on Impression Formation
Jessica Read, Brigham Young University Communications As the world of online social networking has changed to accommodate public interest, online dating sites have become increasingly popular. With this new trend in social media there has been an increased awareness as to how one might present him or herself in the most favorable way possible through computer mediated stimuli. To find out if nonverbal cues played a significant role in online impression formation, we had males and females randomly assigned to one of two variables, where they viewed stimuli of a member of the opposite gender. The stimuli that was presented was either a photograph accompanied by a written autobiography about a member of the opposite gender, or a video of the person reading their own autobiography, which allowed for the presence of nonverbal cues. Participants rated the subjects in the assigned stimuli on a number of different scales ranging from trustworthiness to sexual attractiveness based on their first impressions. Results showed no significant differences between the presence of nonverbal cues in the video stimuli or the photographic stimuli, reasoning for the indifference participants had towards the nonverbal cues is discussed. However, there were significant gender differences among the first impressions formed, other findings are presented.
Pick On This, Make A Change: Helping Prevent Youth Bullying through Grassroots Public Relations
Sydney Tycksen, Utah Valley University Communications An award winning research project, this summary highlights research conducted by Communication students at Utah Valley University of a grassroots public relations campaign created to increase awareness among middle school students, parents, educators, and community leaders of the serious short and long term consequences of youth bullying. The study also demonstrates how the campaign informed audiences of the steps they should take to help prevent bullying. The goal of the research was to understand the short-and-long term effects of bullying, types of bullying, and the prominence of bullying in the surrounding community where the research was conducted. A public relations strategic communication plan was developed based on the research to change bullying behavior in the community. The campaign aimed to spread awareness of the short and long term effects of bullying and outline the steps to report and prevent bullying through the development of strategies and tactics. These steps help students, parents, educators, and community members understand bullying, recognize the signs and types, and know the appropriate authority to whom to report the behavior. This presentation will show how the research provided the students with the information needed to establish measureable objectives for the campaign, reach their key publics and provide an evaluation of the strategies and tactics used to meet campaign objectives. The document reviews the outcome and evaluation of each strategy and tactic implemented during the campaign, including media relations and social media tactics, The summary concludes with an overview of how campaign objectives of teaching key publics how to take steps to prevent bullying were achieved due to thorough research and understanding of how to effectively use messaging to generate behavior changes within the key public.
A Novel Romance: Parasocial Interaction, Attachment Style, and Jealousy in female readers’ romantic relationships
Emma Josey, Dixie State University Communications Romance novels seem to be a staple in the devoted reader’s array of books and have remained an extremely popular genre throughout the centuries. Not only are the actual stories appealing to the readers, but some readers go a step further and interact with or create a relationship with characters themselves. A phenomenon called parasocial interaction. This research study seeks to discover if the parasocial interactions female romance novel readers experience relate to a practice of a particular attachment style and jealousy in their romantic relationships. These characteristics are important to the health and sustainability of people’s romantic relationships, and this study seeks to learn whether or not the quasi relationships romance novel readers create with characters influences those relationships.
Communication & Single Parent Families; Support Programs Impact Communication Between Parents and Children.
Indigo Klabanoff, Dixie State University Communications With globalization and the minority population changing, it is extremely important to learn the real statistics that are out there when it comes to single parenting. The most important thing though, is to figure out is which communication styles work in healthy communication, with single parent families.
The Need for Teacher Evaluations in High Schools
Tyler Mathis, Brigham Young University Education We need to improve our educational system through giving our teachers more chances to be given constructive feedback through teacher evaluations. As teachers receive feedback and are put through effective teacher evaluations their performance will improve and the upcoming generation will be more educated. This will greatly beneficial to the future of our society as a whole. Teacher evaluations is an important topic to raise awareness of to help produce effective and beneficial teaching to the upcoming generation. The topic I will address is how we can make teacher evaluations more effective by exploring ways to quantitatively measure teachers’ effectiveness through examining student gains. I will also examine why implementing teacher observations will be an asset to teacher performance and a necessity in teacher evaluations.
Mother and Child Factors Influence on Parent Language
Kristin Murphy, Utah State University Education Past research shows that parents interact more positively with their children and use more supportive language during play than during teaching interactions (Kwon, Bingham, Lewsader, Jeon, & Elicker, 2013). Children with normal language development tend to have parents who use more language supporting speech, (Vigil, Hodges, & Klee, 2005) than parents of children with language delays. The specific research question addressed in this study is: Do maternal (maternal depression, education levels, parenting stress) or child factors (language development, social-emotional development) influence maternal language behaviors in teaching and play contexts?
Family Write Night
Michelle Fordham, Utah Valley University Education A Family Write Night is an opportunity for teachers, students, and parents to come together to learn about the different stages of writing development and what writing does for the student at any level. Since writing will strengthen and enhance the student in other literacy skills and knowledge, bringing these students and families together in a friendly, casual atmosphere to provide enjoyable, non-assessed activities builds confidence in a writer’s sense of who they are, their voices as writers, as well as developing critical thinking skills. Parent and family involvement is a key component of this activity. Having families, students, and teachers working together to encourage writing at home builds strong family bonds while strengthening writing skills.
Connecting to the Community: Service-Learning Methods in an ESL Classroom
Chelsey Funk, Utah State University Education High school English as a Second Language (ESL) students often feel separated from their schools and communities. These feelings of separation can lead to low engagement and low achievement despite the students’ desire to do well in school. One method used to counter low engagement in mainstream classes is service learning, but there is little research on service learning with ESL students. In this study, an existing group of 9th grade ESL students was taught and observed to determine the feasibility and effectiveness of using service-learning methods. The project endeavored to tie academic work to community involvement and therefore increase student engagement and academic confidence. Throughout the implementation of the service-learning project, students displayed increased classroom involvement and reported improvements in attitudes and self-assurance. The methods and procedures described in this study can be adapted to larger class sizes and a variety of projects in order to increase engagement and academic confidence in ESL students.
Peer Mentor Successes in a Low-performing, Upper Division Science Course
John Lorz, Utah Valley University Education How about a 20% increase in the class average on the mid-term exam compared with the previous two academic years of the same course? In this session two students share their experiences as (newly piloted) peer mentors in a low-performing, upper division genetics class. Student attitudes towards genetics improved and both mid-term and final grades increased by double-digit percentages. Not only did these peer mentors increase student success, but also experienced a personal developmental opportunity in preparation for graduate school, including this conference presentation and an anticipated peer-reviewed publication to follow.
The Parent-Teacher-Student Triad in Mexico
Jonathan Welling, Brigham Young University Education The demographic shift of Mexican immigrants within the public school system in the US has created a great need for teachers to better understand the expectations that immigrant families bring with them from their education system in Mexico. This research provides contextual information to educational stakeholders in the US to better accommodate to the needs of immigrant students from Mexico. This study explores the norms, roles and expectations of teachers, parent and students in the education system in Irapuato, Mexico. Data was collected from observations and interviews with teacher, parents and students from three different public high schools in Irapuato, Mexico: CBTis- a technical school, The Official Preparatory School of Irapuato- a standard public school and SABES- a small rural school. Analysis was done using a systematic approach of open coding to identify emergent themes. Preliminary results provide contextual information explaining the expectations parents hold for the teachers in Irapuato, Mexico. The data is valuable in understanding the norms, expectations and perceived roles held immigrant Mexican families. Applications of this data may be used to facilitate both collaboration between teachers and Mexican immigrant parents and the adjustment of immigrant students to a new educational system.
Learning Two Languages: A Longitudinal Investigation of Discourse Skills for Spanish-English Bilinguals
Stone Samantha, Utah State University Education The present study investigated language growth over the course of 3 years for 50 Spanish-English Bilingual children who were learning English as their second language. Children were asked to retell a story in English and in Spanish at 6 time points (before and after Kindergarten, First, and Second Grades). The stories were transcribed and utterances were coded as to whether they contained mazing behaviors such as revisions, false starts and corrections and also coded for the level of syntactic complexity (simple or complex) they contained. Simple sentences contained one main verb, and complex sentences contained two or more main verbs. The presence of mazing is thought to indicate hesitation or difficulty in lexical retrieval and might be expected to occur more in complex than simple sentences. Further, we hypothesized that children would evidence more mazing behaviors in their non-native language (English) than their native language (Spanish). Ultimately, we theorized that children’s use of mazes in English would decrease over time, as they became more proficient in their second language (English). Some of the children were receiving instruction in schools classified as “English Immersion” models, and others were in schools that incorporated a “Transitional” approach to instruction. Results are discussed in terms of current theoretical models of bilingual language acquisition and variations in outcomes as a function of current instructional models.
English Language Learners in a Kindergarten Classroom: How pre-service teachers can help them improve reading competency
Shawnie Cram, Dixie State University Education English Language Learners (ELL) are confronted with many challenges such as insufficient language proficiency, lack of content knowledge, and adjusting to a new culture. Classroom teachers make efforts to effectively work with these students so they can become a vital member of the classroom community. However, if there is only one teacher in a classroom, they often do not have the time to assist the ELL at an adequate level. Using the participatory action research approach, this paper examines the ways in which a pre-service teacher can assist the classroom teacher by clearly identifying the goal for the ELL student. The goal set by the classroom teacher for this *ELL student is to reach grade level reading competency by the end of the academic school year. Through comprehensive discussions between the classroom and pre-service teacher, the methods and strategies based on Second Language Acquisition theories were decided to be implemented as tools of instruction. The pedagogy of reading across curriculum in a kindergarten classroom is utilized as the basic mode of instruction as the pre-service teacher and the classroom teacher collaboratively use different methods and strategies. The current data of the action research indicates that in three months, the ELL will reach approaching grade level proficiency with the assistance of the pre-service teacher. By the end of the academic school year, the author anticipates the ELL will demonstrate his reading competency at grade level.
Examining Student Performance Related to the Use of E-text/Course Content in Business School Classrooms
Shadlan Gale, Utah Valley University Education This paper presents ongoing research comparing the learning performance of students using online and electronic textbooks/course content (e-text) for business-related classes versus students using traditional, hard-copy textbooks. In fall 2013, the Woodbury School of Business (WSB) at Utah Valley University (UVU) converted over fifty courses to e-text only. The WSB made this transition in many of its classes for various financial reasons as well as to provide students with a more interactive way of learning course material through the application of the additional learning tools that can only be found within the e-text platforms. In a previously published paper, the authors showed that no statistical difference was found in test scores for students at UVU taking a class which implemented the use of e-text among three different delivery types: live, hybrid, and online. This paper focuses more on discovering if student performance and test scores change by using e-text versus hard-copy textbooks and not in relation to the delivery type of the course.
Examining the Faculty Experience Related to the Use of E-text/Course Content in Business School Classrooms
Shadlan Gale, Utah Valley University Education This paper presents ongoing research to examine faculty experience and attitudes toward the implementation of electronic textbooks/course content (e-text) for college courses. In fall 2013, the Woodbury School of Business (WSB) at Utah Valley University (UVU) converted over fifty courses to e-text only. The WSB made this transition in many of its classes to reduce costs and provide students with more interactive course materials through additional learning tools found within the e-text platforms.
Use of Discourse Analysis to Identify Misconceptions in an Engineering Statics Course
Christopher Green, Utah State University Education Statics is a gateway engineering course. Many students use their performance in a statics course to evaluate and judge their desire to continue within an engineering field. Students’ performance can be adversely impacted by misconceptions they may have regarding class content and analysis techniques. Feedback from instructors can help students navigate through their misconceptions. It is critical that this feedback be concise and timely to prevent a slip in self-efficacy, or an increase in their frustration. Both factors can negatively impact a student’s desire to persist in engineering. Implementation of online learning logs allows students a timely communication avenue that can reveal to the instructor indications of such factors. This study is designed to explore common misconceptions exhibited through learning logs in a pre-professional engineering statics class. Ninety student logs were consensually evaluated in a fall 2013 statics course delivered at Utah State University. A “discourse analysis” technique was used to review learning log data to discover students’ trouble areas within the class. Results indicate typical stumbling areas that students encounter in a statics course and allow insight into specific instruction areas that need to be refined to better deliver content to the class as well as individuals.
Evaluating the Utility of the Teacher Behavior Checklist as a Tool for Assessing Graduate Instructor Performance
Jessica Hill, Utah Valley University Education The transition to junior faculty member can be difficult for graduate students (Sorcinelli, 1992). Despite significant teaching requirements for most assistant professor positions, many graduate programs minimize teaching experiences. Due to this climate, the developmental process of novice graduate instructors is poorly understood (McKeachie & Svinicki, 2010). We investigated the utility of the Teacher Behavior Checklist (TBC), a measurement tool developed by studying master teachers (Buskist et al., 2002), as a means to evaluate classroom performance of first-time and novice graduate instructors (GIs).
How a Small Group of Middle School Students Engaged with Data and Evidence While Addressing a Local Water Quality Issue
David Turner, Utah State University Education Problem based learning is an approach to education where students develop solutions to authentic problems (Hmelo-Silver, 2004) with support from scaffolding (Wood, Bruner, & Ross, 1976; Reiser, 2004). Computer based scaffolding helps students organize thoughts and arguments while solving problems (Belland, Glazewski & Richardson, 2008). We examined how students from one small group constructed order in their interactions and arguments as they solved an environmental issue using a stakeholder lens.
General Biology: Can Alignment Make Students More Successful Critical Thinkers
Skylar Larsen, Utah Valley University Education In science education, greater learning gains have been associated with engaged learning strategies over traditional lecture formats. This approach facilitates development of higher-order cognitive skills (HOCS; critical thinking and application of knowledge) which are not only imperative for all successful scientists but necessary for every citizen functioning in our society. Development of these HOCS, however, is not accomplished in some classrooms due to lack of alignment of learning objectives and evaluation, or lack of assessment of these skills entirely. Specifically, we asked how do learning goals and objectives align with assessments, and are learning gains on HOCS better achieved by students in more aligned classrooms tested with higher-cognitive level assessments?
Magnetic Susceptibility of Tree Leaves as a Simple, Cost-Effective Means of Monitoring Air Quality
Lucas Lloyd, Utah Valley University Physical Sciences The high cost of air quality monitoring stations makes it difficult for citizens or local governments to monitor air quality in their own neighborhoods. For example, Utah County, Utah, with an area of 2141 mi2, has only four air-quality monitoring stations: (1) north Provo close to both Provo High School and Brigham Young University (2) Spanish Fork Airport (3) near State Street in Lindon (4) just south of SR-92 on 6000 W in Highland. The air-quality stations monitor levels of CO, NO2, O3, PM-2.5 (particulate matter smaller than 2.5 microns), and PM-10. The objective of this study is to find a much cheaper method of measuring air quality. The objective was addressed by measuring the magnetic susceptibilities of 10 replicates each of the leaves of 12 species of trees (cypress, crab apple, elm, flowering pear, green ash, honey locust, linden, Norway maple, pine, red maple, Russian olive, spruce) collected within a two-mile radius of each of the four air-quality monitoring stations in Utah County. After air-drying and crushing the samples, both low-frequency (0.46 kHz) and high-frequency (4.6 kHz) magnetic susceptibilities were measured with the Bartington MS3 Magnetic Susceptibility Meter. The best correlations between tree leaf magnetic susceptibilities and air-quality parameters were between the three-year average of PM-2.5 and the high-frequency magnetic susceptibility of leaves of pine (Pinus aristata) (R2 = 0.87) and Norway maple (Acer platanoides) (R2 = 0.86). The correlation was used with measured high-frequency magnetic susceptibilities of pine to estimate PM-2.5 in two unmonitored locations heavily impacted by highway traffic (corner of 800 N and I-15 and corner of University Parkway and I-15, both in Orem, Utah) on one day in August 2013. It was found that estimated levels of PM-2.5 were 9.5 µg/cm3 and 8.9 µg/cm3, respectively, which were within the EPA PM-2.5 Standard of 12.0 µg/cm3.
Catalysis of the Reduction of Sodium Borohydride with Microenvironments of Gold Nanoparticles
Frederickk Sudbury, University of Utah Physical Sciences Triphenylphosphine stabilized gold nanoparticles were synthesized using a method developed previously by the Jennifer Shumaker-Parry group. Aminated silica colloids were obtained from the Ilya Zharov group. The gold nanoparticles were adhered to the silica colloids using a method developed for another purpose by the Zharov group. The presence of the particles on the silica colloids was confirmed using both scanning and transmission electron microscopy. The catalytic activity of the gold nanoparticles both with and without adhesion was investigated. It was found that free nanoparticles had significant catalytic activity, in agreement with previous research. Gold nanoparticles attached to silica colloids do not seem to exhibit the same level of catalytic activity as the free particles. It was also found that not all the gold nanoparticles adhered to the surface of the silica particles. Experiments were conducted to determine if there was a critical concentration of silica colloids that would allow for high levels of adhesion of the gold nanoparticles. It was found that only by adding a significant excess of silica colloids to the solution can all the gold nanoparticles be removed from the solution. It was also found that the silica can be saturated with gold nanoparticles by including a small amount of them in a very concentrated gold nanoparticle solution. Further studies for functionalization of the silica colloids and the ability to physically isolate the silica with gold nanoparticles from free nanoparticles are currently in progress.
Patterning and Functionalizing Carbon Nanotube Forests for Antigen Detection
Benjamin Pound, Utah State University Physical Sciences Carbon Nanotube (CNT) Forests are vertically grown carbon nanotubes. They can be as tall as millimeters, with radii from less than one nanometer (single-walled) to tens of nanometers (multi-walled). Their high surface area to volume ratio provides a unique material system for biosensor applications. However, the CNT surface does not provide covalent bonding sites to many antibodies of interest. One approach is to attach linker molecules with aromatic rings via π-stacking to the CNT surface and activating the linker molecules to bind covalently to specific antibody molecules. Unfortunately, the conventional solution-based functionalization approach often leads to collapse of the CNT forest and hence a significant loss of binding sites. In this presentation we demonstrate that CNTs can be lithographically defined to form various structures that are resistant to liquid-induced collapse. We show that the CNT forest can be functionalized with 1,5-diaminonaphthalene as a linker molecule and its coverage can be characterized by fluorescence spectroscopy.
General Approach for Engineering Small-Molecule-Binding DNA Split Aptamers
Alexandra Kent, University of Utah Physical Sciences Prescription drug overdose and abuse is a leading cause of death in the United States. It is a serious issue and has become increasingly problematic as opioids are being prescribed at a higher frequency. For this reason, fast, accurate detection of small drug molecules is crucial. The current standard for use in clinical drug detection is an enzyme-linked immunosorbent assay (ELISA) that uses a series of antibodies to bind to the target drug and enable quantification via a colorimetric output. However, the antibodies used in an ELISA often cannot distinguish between similar molecules. Aptamers are short sequences of DNA that have emerged as a promising alternative to antibodies, as they are generated in vitro, where negative selections can be used to increase target selectivity. These aptamers can be cleaved to make split aptamers that only assemble in the presence of the target small molecule. One inherent problem of this system is the need for split aptamers that are selective for their small molecule targets. While there are many known aptamers, there are only a few known split aptamers that bind small molecules. Separating aptamers with a privileged, three-way-junction structure provides a reliable method to generate new split aptamers.
Creation of coherent complex pressure measurements through overlapping scan-based measurements
Jazmin Myres, Brigham Young University Physical Sciences In scan-based array measurements, stationary reference sensors are needed to temporally correlate the different measurement scans and produce coherent complex pressure fields. Because the number of references required increases with the number of subsources contributing to the sound field, an extended, partially correlated source comprising many ill-defined sources can result in significantly increased measurement complexity. A different approach to creating spatiotemporally coherent pressures is demonstrated here. Scan based measurements of a partially coherent line source have been taken in an anechoic chamber. This experimental data has been used to explore “stitching” together a complex pressure field by spatially overlapping measurement scans instead of using separate reference channels. Various methods of stitching have been explored and the most robust method identified. Unwrapping of intrascan phases is first accomplished with a two-dimensional phase unwrapping algorithm. Individual scan positions are then stitched together using median phase differences between multiple adjacent scans to create coherent planes of data. Amplitude-stitching is done by averaging across scans and preserving the integrated squared pressure across the overall aperture. This method has been verified using reference microphones. This stitching method has been applied to scan based measurements of a military aircraft, exhibiting its effectiveness dealing with a partially correlated complicated source. This method works well for low-frequency jet data, where there is not a ground-based interference null creating a physical phase discontinuity. This technique provides direction for efficient experimental design for scan-based array measurements of extended sources. [Work sponsored by ONR.]
Environmental and global carbon cycle signals recorded in 6 million year carbon isotope record from the Paleocene Black Peak Formation, Big Bend National Park
Stephen Ruegg, University of Utah Physical Sciences The Black Peaks Formation (BPF) from the Tornillo Group in Big Bend National Park (BBNP) is comprised of a series of stacked paleosols and sandstone channels deposited by a fluvial system in a sub-tropical intramountain basin during the Laramide orogeny. Paleosols constituting the BPF display alternating drainage and development conditions. The BPF is bounded by the Late Cretaceous Javelina Formation and the Early Eocene Canoe Formation and is therefore thought to be of Paleocene age (65.5-55.8 million years ago). The BPF is an interesting target for paleoenvironmental reconstruction because little data have been generated from the Paleocene for sub-tropical regions, limiting the validation of global climate model predictions in these regions. However, previous attempts to resolve the age of the formation using biostratigraphy, magnetostratigraphy and chemostratigraphy gave ambiguous results limiting the potential of the BPF for paleoenvironmental reconstruction. We analyzed the carbon isotope ratio (δ13C ) of carbonate nodules collected from pedologically distinct paleosols throughout the BPF. δ13C of carbonates nodules found in reduced black paleosols are systematically 3-4‰ lower than δ13C from non-black paleosols from neighboring stratigraphic intervals. We hypothesize that this isotopic difference is related to the lower contribution of atmospheric CO2 to soil CO2 in water-logged and/or poorly drained black soils. Large-scale stratigraphic patterns of carbon isotope variations in carbonate nodules from non-black paleosols throughout the BPF strongly resemble well-documented secular changes in δ13C values of marine carbonates for the Paleocene. Several recognizable features are present in both curves, including the Paleocene Carbon Isotope Maximum (PCMI) and possibly the Late Danian carbon isotope excursion (LDE). These features provide a new basis for correlation of the BPF to the global geological timescale, and suggest that the Formation preserves a 6 million year record of deposition and paleoenvironmental conditions spanning the majority of Paleocene time (63-57 million years ago).
Evolution of Burrowing Mayflies: Tusks be gone
Stephanie Bartlett, Utah Valley University Physical Sciences Ephemeroptera, commonly referred to as mayflies, are found throughout the world. Within the order of Ephemeroptera resides a superfamily, Ephemeridea, commonly called burrowing mayflies. This common name was acquired due to certain physical and behavior characteristics present as nymphs. Ephemeridea nymphs live in the silt of aquatic environments and have adaptations for burrowing which include strong legs, as well as mandibular tusks. One exception to this is the family Behningiidae, which burrow, but lack the commonly associated mandibular tusks. Morphological data supported Behningiidae as sister to the other tusked burrowing mayflies, indicating that first burrowing behavior evolved and was later followed by the development of tusks(McCafferty; 1975 and 2004). While morphological data provides important insights into the evolution and phylogeny of mayflies, the development of molecular phylogenetics offers new contributions when determining evolutionary relationships within this superfamily. Objective: The purpose of this study is to investigate the relationships of the families of burrowing mayflies in order to test the hypothesis of tusk evolution. Methods: The specimens were acquired from collection efforts and colleagues. For each specimen the following laboratory procedures were carried out: DNA extraction, gene amplification via polymerase chain reaction, visualization via gel electrophoresis, and DNA sequencing. The genes targeted for sequencing included 12S mitochondrial rDNA, 16S mitochondrial rDNA, 18S nuclear rDNA, 28S nuclear rDNA, H3 nuclear protein coding, and CO1 mitochondrial protein coding. Data was also acquired from Genbank in order to augment missing data. Taxon sampling consisted of around 20 ingroup and 5outgroup taxa. Phylogenetic relationships were estimated using Maximum Parsimony, Maximum Likelihood, and Baysian methods. Conclusion: The families Behningiidae, Potamanthidae, Palingeniidae were supported as monophyletic. Behningiidae nested well within the other burrowing families. Hence, tusks evolved and were subsequently lost in the family Behningiidae even though it retained the burrowing lifestyle in the nymph.
Nondestructive Isolation of Forensic Analytes with Ionic Liquids
Mattie Jones, Dixie State University Physical Sciences New methods aimed at forensic analysis of sensitive, minute samples are critical to the intelligence community. In particular, successful extraction of dyes from materials found at crime scenes will provide innumerable benefits for matching, identifying, and finding origins of these materials and dyes. Current methods of isolating components of samples by their unique chemical properties are lengthy and often destroy important forensic evidence. Ionic liquids possess the necessary chemical properties to ensure efficient extractions, while maintaining the forensic signatures of the original materials. They also provide a one-pot approach that avoids intermediate species and increases analyte yield while extracting and separating constituents in a more efficient manner. By combining traceable dyes with an ionic liquid, the versatility of single-component extraction-separation-identification was demonstrated. Analysis using absorption and fluorescence spectroscopy validated complete extraction and recovery of trace analytes. Following extraction and isolation, identification by infrared spectroscopy has provided evidence of preserved quality and complete separation of material and dye. This novel approach to forensic analysis is advantageous particularly when sample sizes are extremely limited, but it can be readily scaled to larger applications. Developing a simple and affordable method of achieving specific molecular interactions provides a solution for often unidentifiable evidence in crimes. Harnessing the versatility of ionic liquids in a high-yielding recovery and efficient single-pot methods will enhance forensic abilities for the intelligence community and forensic investigators.
Investigating Anthropogenic Impacts on the Utah Lake-Jordan River Transition Zone Using a Multi-proxy Approach
Buchanan Kerswell, Utah Valley University Physical Sciences This project is designed to investigate anthropogenic impacts on the geochemistry and physical characteristics of Utah Lake-Jordan River transition zone, in Utah Valley, Utah. The zone has experienced dramatic, multifaceted shifts since European settlement in 1847, especially in recent decades. Our chosen study location is uniquely situated to capture changes recorded in the sediment cores due to land use, nutrient enrichment, vegetation shifts and river dynamics since pre-settlement.
Methods to decrease error in conductivity measurements of highly disordered materials
Phillip Lundgreen, Utah State University Physical Sciences By developing a low-noise, high-voltage battery power supply, system noise has been reduced, increasing accuracy of conductivity measurements of highly disordered insulating materials. The method involves a simple parallel plate capacitor setup with the sample sandwiched between electrodes, a voltage potential applied to one electrode, and a measurement device applied to the back electrode measuring current. Previous methods involved use of a commercial power supply with a claimed low noise and high linearity, but with a low AC output ripple. At high voltages (1000 V), however, the noise became apparent in the readings and an unacceptable uncertainty was introduced in our precision conductivity measurements. Through the use of a stable dc battery high-voltage power supply, we were able to reduce noise in current measurements and achieve a more accurate measurement of conductivity for various samples.
Mode transitions in strings with an abrupt change in mass density
Nathaniel Wells, Utah Valley University Physical Sciences Previous research with bottle-shaped thermoacoustic prime movers has revealed hysteresis with transitions to higher modes as the cavity length is varied. A string with an abrupt change in mass density was studied to investigate potentially similar behavior. Three base guitar strings were studied at three different tensions with weights of 25, 30, and 35 lbs. Each string consisted of a “thin side” that was stripped to the stainless steel core and a “thick side” with an outer wrapping of nickel around the core. The strings studied had diameters of 0.65, 0.45, and 0.50 mm on the thin side and 2.14, 1.31, and 1.24 mm on the thick side, respectively. An anchor was attached on one end of a short board with a pulley at the other for hanging the weight. The end of the thick side of the string was attached to the anchor, and the string was guided over the pulley, with the change in mass density occurring approximately 12 cm from the pulley. Measurements were taken after placing a glass jar under the thick end of the string, between 42 cm and the position of the change in mass density, in 3-cm steps. The string was plucked and the dominant frequency was recorded with a microphone at each location. Frequency data is generally consistent with a solution to a 1D wave equation. Preliminary results indicate mode transitions occurring for all strings, with several hysteresis region candidates.
Correlation analysis of military aircraft jet noise
Zachary Anderson, Brigham Young University Physical Sciences Correlation analysis is useful in extracting spatiotemporal relationships between signals and can be used to examine features of near-field jet noise for source properties. Characteristic correlation envelopes determined by Harker et al. [JASA 133, EL458 (2013)] can be used to relate correlation lengths to fine and large-scale turbulent structures. As an extension, cross-correlation shows spatial variation in jet noise and further reveals the transition between short (fine-scale) and long (large-scale) correlation lengths. These analyses are applied to a military jet dataset of a ground based linear microphone array positioned 11.6 m from the jet axis. Correlation analyses over multiple engine conditions and observation directions are reported. In particular, a maximum correlation coefficient greater than 0.5 exists over a range spanning multiple wavelengths in the region of greatest overall sound pressure level at military power. [Work supported by ONR.]
Analysis of Untriggered Small Events in the HAWC Telescope
Ian Sohl, University of Utah Physical Sciences Current software in the High Altitude Water Cherenkov (HAWC) Telescope data collection system only triggers saving of events that pass a specified number of hits and energy. Our analysis of the untriggered (and unsaved) data will identify the number of potentially significant events that are bypassed by the existing software. By the application of a sorting function onto current Monte Carlo generated data, we can categorize incoming events into various types of particles, primarily muons, while also filtering out randomized noise from the photomultiplier tubes used in HAWC. Due to the relatively low rate and energy of the photomultiplier tube noise, many of the significant events for the untriggered set are potential useful particles. Our triggering algorithm, based on the energy, timing and saturation of the tanks is primarily focused on separating muons from the bulk of data. These raw rate data for small events are a relatively unexplored area for HAWC and measurements can be useful for a variety of calibration tasks for the telescope. They can be useful for understanding the impact of the atmosphere on the telescope’s data collection, as well as the triggering of the photomultiplier tubes through secondary sources. This untriggered data can also be used in a variety of useful forms not directly related to HAWC’s primary usage goals, primarily solar physics. Due to the relatively low energy and hit count from solar events, most of the data are thrown away by the triggering algorithm.
Evaluation of potential impact of tar sands mining on the integrity of groundwater quality in PR Spring, Uinta Basin, Utah
Mallory Millington, University of Utah Physical Sciences Groundwater in the western United States is a limited and important resource for agriculture, industry, and residents alike. Knowing the movement of groundwater is critical to understanding the potential of groundwater contamination from human activities. While groundwater flow is difficult to quantify, it typically recharges in high elevation and discharges towards lower elevation. The first commercially-approved tar sands mine in eastern Utah is located on a ridgetop in the PR Spring area within the high plateaus on the south rim of the Uinta Basin. To evaluate the potential of groundwater contamination due to tar sands mining a study was conducted to understand groundwater flow in the PR Spring area, specifically the canyon directly south of the tar sands mine called Main Canyon. Water samples were taken from four groundwater springs at elevations ranging from 7040 to 8040 ft in or near Main Canyon. Water quality measurements taken in the field showed that the lower springs exhibited higher conductivity (900 vs. 636 μS/cm) and lower dissolved oxygen (30% vs. 88% saturation) than the higher elevation springs. This suggests that the lower springs have had a greater amount of water-rock interaction and so are chemically more evolved than the springs at higher elevations. SF6 age dating indicated that the high elevation springs are younger than the lower elevation springs, 5.5 vs. 16.0 years since recharge respectively. The field parameters and SF6 age data all indicate that higher elevation springs are younger and less chemically evolved than the water at lower elevations. This indicates that the springs in Main Canyon are sourced from local recharge at the ridgetops. Given these findings the tar sands mine should consider taking preventative measures to protect groundwater resources.
Wavelength Detection from Filtered Photodiodes
Nils Otterstrom, Brigham Young University Physical Sciences Filtered photodiodes show potential as inexpensive laser wavelength meter. Photocurrents are measured digitally. The photocurrent is digitized using externally controlled integration times to achieve the highest precision possible from the digital to analog converters on the photosensor chip. Using an algorithm we’ve developed and calibrated intensity curves, we can precisely calculate wavelength from the output of the different photodiodes. Limitations due to etaloning from reflections off of the surfaces of the filters were analyzed and effectively mitigated, allowing the device to achieve high precision with a stability of 0.102 nm over several hours.
Characterization of undocumented bonneville shorelines with evidence of possible tsunamis
Brittney Thaxton, University of Utah Physical Sciences There are many undocumented shorelines seen in Utah. As many as 30+ shorelines have been identified along the edges of the basin throughout the state. The purpose of this study is to characterize undocumented shorelines and identify potential evidence for tsunamis that might have occurred in Lake Bonneville thousands of years ago in areas such as Little Mountain, Stansbury Island, and Promontory Point, Utah. Lake Bonneville existed 32-10K years ago and was influenced by the Wasatch fault which was active as early as the Miocene. Scarps of this age are common and range between 15-20 feet in height (Machette, Personius, Nelson, Schwartz, Lund 1991; Dinter, Pechman, 2004a and 2004b). Several faults beneath Lake Bonneville could have produced tsunamis. The more water that is displaced the greater the tsunami will become and leave a greater impact onshore (Dutykh and Dias 2009). The East Great Salt Lake fault cuts NS across Bear River Bay east of Promontory Range. This fault line is an excellent candidate for causing a tsunami during the Lake Bonneville highstand because it is beneath the Great Salt Lake meaning it would have uplifted the entire water column of Lake Bonneville and since it is also close to the Promontory Range, it is likely it would leave tsunamite evidence along the shore. The fault rupture interval is between 3,000 and 3,500 years meaning fault ruptures could produce a tsunami during the lake’s high stand. Tsunamite is the term used for deposits related to tsunamis. The tsunamite features found along the shorelines will be similar to sedimentary features such as normally graded sand, mudstone clasts, and other gravel deposits that are out of place with the known shorelines (Shanmugam 2006). This is a unique opportunity to discover ancient tsunami evidence in Utah, a topic that has yet to be pursued.
How many class ii wells present a risk for induced seismicity?
Isaac Allred, Utah State University Physical Sciences We examine the number and location of Class II wells in the central U.S. to constrain future work on the potential for induced seismicity. The EPA, state oil & gas commissions, scientific papers, and media stories frequently state that there are ~140-160 k Class II wells. Excluding California, we expected to find approximately 120 k wells; but instead found ~ 82 k active injectors in the available databases. State datasets vary in accessibility, availability, and content of well data. Lack of digitized well data also limited our online search, and several states require FOIA requests to be filed. State databases with poor searching and sorting functions further complicated data mining, requiring a well-by-well search, and for several states, well locations and injections were difficult to determine. Common discrepancies between EPA well totals and state database totals appear to be due to counting of plugged and abandoned wells, and wells that are permitted but not in use. No data has been retrieved for about 1,600 wells on tribal lands and Indian Country, and several states would not provide “confidential” well data. Of the active injectors, at least 55 k wells inject into producing, pressure-depleting oil and gas formations and are less likely to generate damaging earthquakes. Of the ~ 16 k non-EOR wells, we found 3,400 wells that inject at depths > 1.8 km, where most M > 3.0 midcontinent earthquakes occur. We will present examples of data from several states, that show the locations and depths of injectors, earthquakes, depth to basement, and we will provide an overview of the public file sharing system of the data. We will search for correlations between the depth of injection, the number of injection wells, recent seismic activity, the nature of the subsurface geology, and regional stresses.
Histone modifications are altered in the renal cortex of ventilated preterm lambs
Adam Blair, University of Utah Physical Sciences Objectives: Histone covalent modifications influence regulation of gene expression. Changes in histone covalent modifications are triggered by abrupt changes in environment, such as preterm birth followed by mechanical ventilation (MV). Whether histone modifications also occur in the kidney of chronically ventilated preterm lambs is not known. We hypothesized that ventilation of preterm lambs affects histone modification in kidneys.
Structural health monitoring of natural arches in the Moab area
Ben White, University of Utah Physical Sciences We evaluated the ambient noise wavefield of select arches in the Moab area as a means to assess changes in their structural health over time. Our measurements revealed that the fundamental frequency of vibration at Mesa Arch and Corona Arch are both in the range of 3 Hz, while other spectral peaks are likely related to higher-order vibrational modes. We use numerical modeling for modal analysis in an attempt to predict and visualize the various modes of vibration and their frequency Resonant frequencies are projected to change with snow or rain loading or after a strong earthquake. By monitoring resonant frequencies over time and under various environmental conditions, our goal is to detect reversible and/or irreversible changes that may accompany damage of these arches.
Use of the Manning Equation to Estimate Stream Discharge through Natural Slot Canyons and Artificial Slots
Jeff Selck, Utah Valley University Physical Sciences Stream discharge through narrow, deep slot canyons can be a major source of groundwater recharge in the arid Southwest. Various state and federal agencies use the empirical Manning Equation to predict the discharge through artificial slots created for diversion of rivers around coal mines. However, it is not obvious that the Manning Equation could be applied to slot canyons or artificial slots as the data base used for development of the Manning Equation did not include either natural streams or artificial structures for which most of the friction occurs along the sides of the channel. The objective of this research is to develop an empirical formula for estimating the Manning roughness coefficient for flow through narrow, deep slots. The objective is being addressed by measuring stream discharge through natural slot canyons in southern Utah that are fed by perennial streams, springs or dam outlets. Based on measurements at ten sites along eight streams, the best estimate for the Manning roughness coefficient is n = 0.873nJ exp(5.108A/w2) where A is stream cross-sectional area, w is stream width, and nJ = 0.39S0.38R-0.16 is the roughness coefficient estimated by Jarrett (1984) for high-gradient streams, in which S is slope of the stream bed and R is hydraulic radius (ft). The new formula estimates stream discharge with a mean accuracy of 44%. On the other hand, Jarrett’s (1984) formula underestimates stream discharge by 1-2 orders of magnitude for aspect ratios A/w2 in the range 0.6-0.7. The new formula will be refined by additional measurements on slot canyons, artificial diversions, and a laboratory hydraulics bench. It is hoped that the new formula will lead to a more realistic design for artificial slot diversions.
Synthesis, Analysis, and Biological Activity of Novel Organoarsenic Products
Jared Weaver, Southern Utah University Physical Sciences Organoarsenic are compounds containing carbon and arsenic. These compounds have been shown to have biological activity and pharmaceutical properties, and some organoarsenic compounds have even displayed potential for aiding in current medical problems up to and including possibilities as anticancer agents. Currently relatively little research is being done on organoarsenic compounds by the pharmaceutical community due to current views from the media based largely upon the toxicity of their inorganic arsenic counterparts (inorganic compounds are compounds not containing carbon), organoarsenic compounds however have significantly toxicity. Also, like with any medicine, toxicity depends predominately upon concentration, and given a high enough concentration organoarsenic compounds would logically follow the same trend. Synthesis of a large variety of novel organoarsenic compounds has been found via a reaction involving a variety of aldehydes or ketones and 2-(Dichloroarsino)benzaminium chloride. Research will focus on synthesis, isolation, and characterization of a library of organoarsenic compounds and then determine their respective biological activities. Synthesis will determine mechanistic requirements of said reaction and will be done to produce a diverse selection of organoarsenic compounds. Compounds will be isolated through precipitation of product and vacuum filtration of formed product. Structure will be determined through IR, NMR, and Gas Chromatography/ Mass Spectrometry, and through X-ray crystallography. Biological activity is suspected with potential for testing via a Kirby-Bauer Disc treatment. It is hypothesized that novel organoarsenic products will be formed by reaction of 2-(Dichloroarsino)benzaminium chloride with all carbonyl compounds containing an alpha carbon with at least one proton used, and that compounds synthesized will inhibit bacterial growth.
Use of Phage and Vancomycin Treatments Against Staphylococcus aureus Biofilms
Kelly Hoerger, University of Utah Physical Science Implant devices such as orthopedic, dental, and cochlear implants are commonly utilized as part of many medical treatments. However, these foreign objects are susceptible to bacterial contamination, thereby putting the host at risk of an infection that is challenging to eliminate due to biofilm formation. Biofilms are formed when a bacterial cell adheres to and colonizes such metal or plastic surfaces. The cells aggregate to form and embed themselves in a thick and protective polysaccharide matrix, making biofilms resistant to many antibiotic treatments.
Effects of Environmental Pollutants on Endophytes in Rumex crispus
Yonic Michaca, Utah Valley University Physical Sciences It is well known that some of the worst air pollution in the country each winter is found along the Wasatch front in northern Utah. This study examines the effects of environmental pollutants on the production of the novel compounds produced by the endophytes found in Rumex crispus. The Rumex crispus plant was selected due to its natural medicinal uses. It is anticipated that environmental pollutants have an effect on the production of bioactive compounds in order to protect their plant host from foreign pathogens. The theory is that the more stressful environment a plant lives in, i.e. desert climates, high altitude, and man-induced stresses such as pollution, the more bioactive compounds the endophytes produce as a response to protect their plant host. This study analyzes the effects of environmental pollutants along the Wasatch front on the production of novel bioactive compounds produced by the endophytes found in Rumex crispus. Plant samples are also collected from sites near the Wasatch front, but they are not exposed to the same amount of air pollution to be used as a control.
Protein phosphatase (PP) 1 and PP2B do not contribute to palmitate-induced disruption of eNOS enzyme function.
Ting Ruan, University of Utah Physical Sciences Cardiovascular complications are more prevalent in patients with diet-induced obesity and type 2 diabetes. Both of these conditions are associated with elevated levels of free fatty acids (FFAs). Elevated FFAs might precipitate cardiovascular complications by disrupting endothelial nitric oxide (NO) synthase (eNOS) enzyme function. The physiologically abundant saturated FFA palmitate decreases eNOS phosphorylation at serine 1177 (p-eNOS S1177) in a ceramide and protein-phosphatase 2A (PP2A) -dependent manner. p-eNOS S1177 is a positive regulatory site on the eNOS enzyme. As such, p-eNOS S1177 to total eNOS can be used as an estimate of eNOS enzyme function. We sought to determine the extent to which two other phosphatases that are abundant in the cytosol i.e., protein phosphatase 1 (PP1) and protein phosphatase 2B (PP2B) might contribute to palmitate-induced reductions in p-eNOS S1177 to total eNOS. Bovine aortic endothelial cells (BAECs) were treated for 3 hours with 500 uM palmitate or vehicle in the absence and presence of the PP1 inhibitor tautomycin (3 uM). p-eNOS S1177 to total eNOS was assessed using immunoblotting procedures. Palmitate-induced reductions (30±3%, p<0.05, n=3) in p-eNOS to total eNOS were similar in the absence and presence of tautomycin. These data indicate that PP1 does not contribute to palmitate-induced disruption of eNOS enzyme function. Next, BAECs were treated for 3 hours with 500 uM palmitate or vehicle in the absence and presence of the PP2B inhibitor cyclosporine (100nM). Palmitate-induced reductions (31±4%, p<0.05, n=3) in p-eNOS to total eNOS were similar in the absence and presence of cyclosporine. Taken together, these data suggest that neither PP1 nor PP2B contribute to palmitate-induced reductions in p-eNOS S1177 to total eNOS.
The Use of ArcGIS and Shallow Groundwater Monitoring for Stormwater and Irrigation Management with a High Water Table, Springville, Utah
Andrew Fletcher, Utah Valley University Physical Sciences Springville, Utah, is known for its high water table and many freshwater wetlands and springs, which gave rise to the name of the city. Flooding of barns is a common problem among farmers in western Springville, which is just east of Utah Lake. These frequent barn floods are anecdotally linked to high-intensity precipitation events and the common use of flood irrigation. The objective of this study is to determine the cause of barn flooding and to make recommendations for mitigation of barn flooding for individual farmers with whom we are working in this area. The objective is being addressed first by using ArcGIS to determine the watershed of each barn and the NRCS (Natural Resource Conservation Service) Web Soil Survey to map hydrologic soil groups within each watershed. Results from the larger-scale Web Soil Survey will be supplemented with measurements of soil hydraulic conductivity using the SoilMoisture Equipment Model 2800K1 Guelph Permeameter. The above data will be used in the NRCS Curve Number Method to estimate the volume of surface runoff expected in a 100-year 24-hour precipitation event. The objective is also being addressed by installing shallow, hand-augured wells for monitoring the depth to the water table during high-intensity precipitation events and flood irrigation events. The results will be used to develop recommendations for a combination of (1) installation of French drains for diversion of stormwater (2) modification of current irrigation methods (3) pumping and diversion of groundwater. Results and specific recommendations for individual farmers will be presented at the meeting.
Novel Bioactive Compounds Produced by Juniperus osteoperma
Kip Brower, Utah Valley University Physical Sciences Juniperus osteoperma has been reported to exhibit beneficial pharmacological activity against symptoms of diabetes, as a traditional treatment for kidney ailment and the essential oil of juniper berries has also been subject to investigation for antioxidant activities. Endophytes, particularly endophytic fungi, have produced numerous novel bioactive compounds, several of which are currently used as antifungal, anti-bacterial, and anti-cancer agents in organisms other than their plant hosts. This investigation looks into the possibility of endophytic fungi being a means of producing compounds that may be a functioning agent in antioxidant, antifungal, or hyper/hypoglycemic activities of Juniperus osteoperma. The investigation involves samples of Juniperus osteoperma collected from multiple different locations within Utah, and isolates the resident endophytic fungi.
Band gap tunability of protein-based ferrhihydrite nanoparticles
Stephen Erickson, Brigham Young University Physical Sciences “The spherical protein ferritin has often been used to fabricate nanoparticles of various shapes and compositions with its walls. Ferritin occurs naturally with a ferrihydrite (FeOOH) mineral core, but it has also been used to synthesize nanoparticles of several other semiconductors. While the methods for creating these nanoparticles within ferritin are well established, the characterization of such nanoparticles is not. Previous studies on native ferrihydrite core ferritin disagree on the band gap, giving values anywhere from 1.1-3.5 eV, depending on the method. We have used absorption spectroscopy to measure these band gaps with an unprecedented accuracy of up to .01 eV. This method also allowed us to determine that ferrihydrite nanoparticles are indirect gap semiconductors. By employing this method on particles of various sizes, we have shown the effects of quantum confinement, resulting in variations in the band gap. We also provided the first ever direct evidence that ferritin works to crystalize its core with time, an effect that has long been theorized but never observed. By characterizing the effect of size and time on nanoparticle band gap, we have shown the potential for selectively tuning that gap. This opens up a world of possible applications in light harvesting and photo detectors. By controlling the band gap, we will be able to select which wavelengths of light are absorbed, allowing for full spectrum photovoltaic cells and wavelength specific optical detectors. Future studies will focus on nanoparticles of other metal hydroxides and various anion replacements to further expand our tunable range of band gaps.
Exploring Norbornenyl Solvolysis Rates with Electronic Structure Computational Methods
Byron Millet, Weber State University Physical Sciences The relative solvolysis rates of norbornenyl derivatives have been of interest. To date, only one other norbornenyl compound has been found that solvolyzes slower than anti-7-norbornene. It has been suggested that through-space interactions between π-bonds plays a significant role in stabilizing the carbocations. However, through-space interactions do not account for the similar observed solvolysis rates of nearly identical compounds both with and without adjacent π-bonds. Studies have shown that the stability of these compounds is significantly affected by σ-bond interactions. We report on our current computational study of the relative energies of several norbornenyl compounds with and without adjacent π-bonds to evaluate both π-bond and σ-bond effects on the stability of the norbornenyl cations. The effect of a ketone functional group on the relative stability of the carbocation is also analyzed. The literature solvolysis rates of the various norbornenyl derivatives and the stability of their respective cations is compared. With some exceptions, a correlation was found between the stability of a derivative’s carbocation and its respective rate of solvolysis.