Brielle Woolsey, Brigham Young University
Physical Sciences
A method of forming zinc oxide (ZnO) single crystal hexagonal prisms is derived from a standard sol-gel method. The new synthesis requires water, zinc acetate, and diethanol amine (DEA) to create a zinc hydroxide/zinc hydroxide acetate gel, which forms single crystal hexagonal prisms upon heating. Characterization of the gel was done by XRD as well as by XRD high temperature chamber (HTK) to determine the role of temperature in prism formation. SEM images showed hexagonal prisms were of uniform size (approx. 0.5 — 2 µm). TEM and electron diffraction images showed a change from randomly oriented particles to an ordered single crystal after heating. Ethanol amines, heating of the gel, and the zinc acetate salt proved to be critical to prism formation.